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Cobalt and nickel complexes of a new carborane-substituted bis(phosphanido) ligand have been prepared. Reaction of the cobalt complex with white phosphorus (P 4 ) results in a remarkable fragmentation of P 4  into P 3  and P 1  units.

Synthesis of a carborane-substituted bis(phosphanido) cobaltate(i), ligand substitution, and unusual P4fragmentation

Synthesis of a carborane-substituted bis(phosphanido) cobaltate(i), ligand substitution, and unusual P₄fragmentation