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The first, enantioselective total synthesis of the heterodimeric biaryl antifungal natural product parnafungin A1 as well as 10a- epi -hirtusneanine is accomplished, using a cross-coupling strategy to construct their sterically hindered biaryl cores.

Enantioselective total synthesis of parnafungin A1 and 10a-epi-hirtusneanine