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A non-MOF ionic solid having two types of polyhedral mesopores in a very large crystal lattice is generated from a cationic AuI6AgI3CuII3 complex with  d -penicillamine, showing specific exchanges of counter-anions retaining its single crystallinity.

A mesoporous ionic solid with 272 AuI6AgI3CuII3 complex cations in a super huge crystal lattice