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The outcome of reactions between diborenes and terminal alkynes can be tuned by varying the stabilising Lewis base and/or reaction conditions, to yield either the  anti -hydroalkynylation product or [2 + 2] cycloaddition-derived boron heterocycles.

chemical science

Reactions of diborenes with terminal alkynes: mechanisms of ligand-controlled <i>anti</i>-selective hydroalkynylation, cycloaddition and CC triple bond scission

Reactions of diborenes with terminal alkynes: mechanisms of ligand-controlled anti-selective hydroalkynylation, cycloaddition and CC triple bond scission