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An iridium catalyzed asymmetric hydrogenation of exocyclic γ,δ-unsaturated β-ketoesters  via  dynamic kinetic resolution was developed, providing efficient protocol for enantioselective synthesis of functionalized chiral allylic alcohols.

Asymmetric hydrogenation of exocyclic γ,δ-unsaturated β-ketoesters to functionalized chiral allylic alcohols via dynamic kinetic resolution