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Achiral poly(quinoxaline-2,3-diyl) containing Ar 2 P groups undergo dynamic induction of  M -helical conformation through nonbonding interaction with protected AA such as Ac- l -Pro-OMe, serving as a chiral ligand in asymmetric cross-coupling with up to 95% ee.

Protected amino acids as a nonbonding source of chirality in induction of single-handed screw-sense to helical macromolecular catalysts