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Through the combination of a Ni-catalyzed alkene alkenylboration followed by hydrogenation, the synthesis of congested Csp 3 -Csp 3 -bonds can be achieved. Conditions have been identified that allow for the use of both alkenyl-bromides and -triflates. In addition, the hydrogenation creates another opportunity for stereocontrol, thus allowing access to multiple stereoisomers of the product. Finally, the method is demonstrated in the streamlined synthesis of a biologically relevant molecule.

Construction of congested Csp3–Csp3 bonds by a formal Ni-catalyzed alkylboration

Construction of congested Csp³–Csp³ bonds by a formal Ni-catalyzed alkylboration