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The global minimum of the B 9 O −  cluster is found to have an umbrella-like structure, where the central B atom exhibits transition-metal-like bonding properties, coordinated by a η 7 -B 7  ligand on one side and a BO ligand on the other.

Transition-metal-like bonding behaviors of a boron atom in a boron-cluster boronyl complex [(η7-B7)-B-BO]−

Transition-metal-like bonding behaviors of a boron atom in a boron-cluster boronyl complex [(η⁷-B₇)-B-BO]⁻