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N -PhPABZ successfully cured the brittleness of PMDA-based poly(benzimidazole imide)s.  N -PhPABZ-PMDA film illustrated an extremely high  T  g  of 486 °C and a low CTE of 9.7 ppm K −1 .

N-Phenyl-substituted poly(benzimidazole imide)s with high glass transition temperature and low coefficient of thermal expansion