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An efficient visible light photocatalytic strategy to synthesize  Z -arylvinyl halides from  E -arylvinyl acids using  N -halosuccinimide through a sequential halodecarboxylation/photoisomerization with up to &gt;99/1  Z / E  ratio and 86% yield under mild reaction conditions.

Visible light photocatalytic one pot synthesis of Z-arylvinyl halides from E-arylvinyl acids with N-halosuccinimide