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Iron valences of 129 P-clusters from FeMo/V proteins were analyzed using a bond valence method, supposing the existence of Fe 3+  in a generally considered all-ferrous P N  cluster in solution with excess reducing agent.

Statistical analysis of PN clusters in Mo/VFe protein crystals using a bond valence method toward their electronic structures

Statistical analysis of P^N clusters in Mo/VFe protein crystals using a bond valence method toward their electronic structures