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The Pd–P@Pt–Ni core–shell nanoparticles consist of an amorphous core and a low-crystalline shell. They exhibit the excellent catalytic properties in MOR owing to the double synergistic effects from the core and the nickel species in the shell.

Core–shell Pd–P@Pt–Ni nanoparticles with enhanced activity and durability as anode electrocatalyst for methanol oxidation reaction