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The HER electrocatalytic activity of pentagonal PdX 2  (X = S, Se) can significantly be improved by S/Se and Pd vacancies and can be further regulated by vacancy concentration.

Defect induced electrocatalytic hydrogen properties of pentagonal PdX2 (X = S, Se)

Defect induced electrocatalytic hydrogen properties of pentagonal PdX₂ (X = S, Se)