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Three P,N-rhenium tricarbonyl complexes exhibited photoisomerization upon irradiation at 365 nm, and no CO release was detected. The antibacterial activity is attributed to their singlet oxygen generation, following the same decreasing order: RePNBr &gt; RePNTfO &gt; RePNNBr.

rsc advances

Photochemistry of P,N-bidentate rhenium(<scp>i</scp>) tricarbonyl complexes: reactive species generation and potential application for antibacterial photodynamic therapy

Photochemistry of P,N-bidentate rhenium(i) tricarbonyl complexes: reactive species generation and potential application for antibacterial photodynamic therapy