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The kinetics and mechanism of ethylene and 5-ethylidene-2-norbornene copolymerization catalyzed by  rac -Et(Ind) 2 ZrCl 2  were investigated using 2-thiophenecarbonyl chloride.

rsc advances

Rapid kinetic evaluation of homogeneous single-site metallocene catalysts and cyclic diene: how do the catalytic activity, molecular weight, and diene incorporation rate of olefins affect each other?