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An original method for the synthesis of 2-hydrazonoimidazo[4,5- d ]thiazolone derivatives has been developed based on an acid-induced Dimroth-type N/S-interchange of  N -aminothioglycolurils formed  in situ  into 2-hydrazonoimidazo[4,5- d ]thiazolones.

Dimroth-type N/S-interchange of N-aminothioglycolurils in the synthesis of 2-hydrazonoimidazo[4,5-d]thiazolones