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First-principle theory calculations reveal record coordination numbers of CN = 13 in  D  13h  La©C 13  + , CN = 12 in  C  2v  Y©B 6 C 6  + , and CN = 11 in  C  2v  Sc©B 5 C 6  in planar species, effectively enriching the chemical structures and bonding patterns of planar hypercoordinated complexes.

Metal-centered monocyclic carbon wheel clusters with record coordination numbers in planar species