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Phosphorylated graphene sheets covalently bind, grow and stabilize biphasic anatase–rutile clusters through strong P–O–Ti bridges. The resulting nanocomposites stands as efficient visible-light photocatalysts for the degradation of dyes from water.

Growth of binary anatase–rutile on phosphorylated graphene through strong P–O–Ti bonding affords a stable visible-light photocatalyst