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A simple and efficient cascade reaction was developed for the construction of hydroxy substituted indolizines from pyrrole-2-carbaldehydes and commercially available 4-halogenated acetoacetic esters.

rsc advances

Access to 6-hydroxy indolizines and related imidazo[1,5-<i>a</i>]pyridines through the S<sub>N</sub>2 substitution/condensation/tautomerization cascade process

Access to 6-hydroxy indolizines and related imidazo[1,5-a]pyridines through the SN2 substitution/condensation/tautomerization cascade process

Access to 6-hydroxy indolizines and related imidazo[1,5-a]pyridines through the S_N2 substitution/condensation/tautomerization cascade process