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A novel one-dimensional (1D) hybrid {[Re 6 S 8 (Pz) 6 ][Pb 3 I 8 (DMF) 2 ]}·6(DMF) with hexarhenium cluster cations has been synthesized, and it shows strong broad-band emission with peak at 634 nm.

One-dimensional lead iodide hybrid stabilized by inorganic hexarhenium cluster cations as a new broad-band emitter