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A convenient design of 7,8-dihydro-6 H -5,8-ethanopyrido[3,2- d ]pyrimidines is reported from quinuclidinone, which afforded versatile platforms that were then used to access a variety of original heterocycles.

Aminations and arylations by direct C–O activation for the design of 7,8-dihydro-6H-5,8-ethanopyrido[3,2-d]pyrimidines