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Two decanuclear Ln–Cr clusters  Ln7Cr3  were obtained, which formed a three-dimensional framework with one-dimensional nanopore channel through hydrogen-bond and π-bond interactions.  Gd7Cr3  had a magnetic entropy change of 21.1 J kg −1  K −1  at 5 K, 7 T.

A new family of decanuclear Ln7Cr3 clusters exhibiting a magnetocaloric effect

A new family of decanuclear Ln₇Cr₃ clusters exhibiting a magnetocaloric effect