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Three-reactive centered reagent (TCCA) mediated construction of spirooxindoles through an oxidative rearrangement of various  N -protected tetrahydro-β-carbolines and total synthesis of natural alkaloids (±)-coerulescine and (±)-horsfiline.

rsc advances

TCCA-mediated oxidative rearrangement of tetrahydro-β-carbolines: facile access to spirooxindoles and the total synthesis of (±)-coerulescine and (±)-horsfiline