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Co( ii ), Zn( ii ), and Cd( ii ) complexes supported by bis-pyrazolyl ligands were applied to the ring-opening polymerization of  rac- lactide to produce heterotactic polylactides (PLAs) with superior heterotactic bias  i.e. P  r  up to 0.94 at −25 °C.

rsc advances

Synthesis, structures, and catalytic efficiency in ring opening polymerization of rac-lactide with tridentate vs. bidentate cobalt(<scp>ii</scp>), zinc(<scp>ii</scp>), and cadmium(<scp>ii</scp>) complexes containing N-substituted N,N-bis((3,5-dimethyl-1H-pyrazol-1-yl)methyl)amine ligands

Synthesis, structures, and catalytic efficiency in ring opening polymerization of rac-lactide with tridentate vs. bidentate cobalt(ii), zinc(ii), and cadmium(ii) complexes containing N-substituted N,N-bis((3,5-dimethyl-1H-pyrazol-1-yl)methyl)amine ligands