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An efficient transition-metal-free oxidative C (sp2) –H/C (sp2) –H cross-dehydrogenative coupling  via  C (sp2) –H bond functionalization for regioselective C-3 acylation/benzoylation of 2 H -indazoles with aldehydes/benzyl alcohols/styrenes is reported.

rsc advances

Oxidative cross-dehydrogenative coupling (CDC) via C(sp2)–H bond functionalization: tert-butyl peroxybenzoate (TBPB)-promoted regioselective direct C-3 acylation/benzoylation of 2H-indazoles with aldehydes/benzyl alcohols/styrenes