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The versatile property of the Keggin type POM is the multi-electron transfer that happens during the switching between [PMo 10 V 2 O 40 ] 5−  to [PMo 10 V 2 O 40 ] 27− . This tunable behavior makes it unique, efficient material as a cathode for Na-ion batteries.

rsc advances

Sodium ion intercalation and multi redox behavior of a Keggin type polyoxometalate during [PMo10V2O40]5−to [PMo10V2O40]27−as a cathode material for Na-ion rechargeable batteries