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The stability of perovskite structure type oxides and higth valence state of cations, respectively may be better understood by considering lattice site potential and Madelung electrostatic potential energy.

rsc advances

Revisiting the valence stability and preparation of perovskite structure type oxides ABO<sub>3</sub> with the use of Madelung electrostatic potential energy and lattice site potential

Revisiting the valence stability and preparation of perovskite structure type oxides ABO3 with the use of Madelung electrostatic potential energy and lattice site potential

Revisiting the valence stability and preparation of perovskite structure type oxides ABO₃ with the use of Madelung electrostatic potential energy and lattice site potential