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The Mn/γ-Al 2 O 3  catalyst exhibited excellent performance for NO conversion in the presence of a low ratio of O 3 /NO, which was due to the coexistence of Mn 3+  and Mn 4+  and abundant chemically adsorbed oxygen.

rsc advances

Mn-based catalysts supported on γ-Al2O3, TiO2 and MCM-41: a comparison for low-temperature NO oxidation with low ratio of O3/NO