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We show that 7,7,8,8-tetracyanoquinodimethane (TCNQ) has both intra- and inter-molecular charge-transfer states. They appear in a different manner in the fluorescence, sensitively depending on the nature of solvent molecules.

New aspect of photophysics of 7,7,8,8-tetracyanoquinodimethane and its solvated complexes: intra- vs. inter-molecular charge-transfer