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A (3 + 2) annulation of  trans -2-aroyl-3-styrylcyclopropane-1,1-dicarboxylates with nitriles is reported for the diastereoselective synthesis of 5-vinyl-1-pyrroline derivatives in 60–88% yields.

rsc advances

Tin(<scp>iv</scp>) chloride mediated (3 + 2) annulation of <i>trans</i>-2-aroyl-3-styrylcyclopropane-1,1-dicarboxylates with nitriles: diastereoselective access to 5-vinyl-1-pyrroline derivatives

Tin(iv) chloride mediated (3 + 2) annulation of trans-2-aroyl-3-styrylcyclopropane-1,1-dicarboxylates with nitriles: diastereoselective access to 5-vinyl-1-pyrroline derivatives