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An efficient heterogeneous and green catalyst [HEMTH]H 2 [PMo 12 O 40 ] was prepared to catalysis the oxa-Pictet–Spengler cyclization of arylethanols and aldehydes to afford isochromans with excellent yields using dimethyl carbonate as a green solvent.

Heteropolyacid ionic liquid heterogeneously catalyzed synthesis of isochromans via oxa-Pictet–Spengler cyclization in dimethyl carbonate