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An easily prepared phosgene probe, 5′-amino-2-(2′-hydroxyphenyl)benzimidazole ( P1 ), is designed and studied. Based on ESIPT mechanism,  P1  exhibits ratiometric, sensitive and selective detection of phosgene both in solution and gas phase.

An amino-substituted 2-(2′-hydroxyphenyl)benzimidazole for the fluorescent detection of phosgene based on an ESIPT mechanism