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The heterocyclic donor molecule 2,4,7,9-tetramethyl-1,6-dithiapyrene (TMDTP) has been synthesized in five steps. The charge-transfer complex, TMDTP–TCNQ, has been prepared and the salt, (TMDTP) 3 (PF6) 2 ·2THF, obtained by electrocrystallization.

rsc advances

A new donor for charge-transfer systems: synthesis and properties of 2,4,7,9-tetramethyl-1,6-dithiapyrene (TMDTP) and structure of (TMDTP)3(PF6)2·2THF and TMDTP–TCNQ