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Complexation of metal ions by a ligand bearing a azobenzene linker yielded two types of complexes: an [M 2 L 2 ] 4+  metallocycle and an [M 4 L 6 ] 8+  tetrahedral cage, which can be further converted into libraries of mononuclear [M(L′/L′′)  n  ] 2+  species.

inorganic chemistry frontiers

Gating the photoactivity of azobenzene-type ligands trapped within a dynamic system of an M4L6 tetrahedral cage, an M2L2 metallocycle and mononuclear MLn complexes