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Rhodium complexes with functionalized NHC ligands catalyze the polymerization of phenylacetylene to give very high molar mass stereoregular polymers. Surprisingly, some chloro-complexes are much more active than related cationic precursors also.

Polymerization of phenylacetylene catalyzed by rhodium(i) complexes with N-functionalized N-heterocyclic carbene ligands