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A stereoselective synthesis of the monodeuterated methyleneaziridine shown allowed the stereochemical course of formal S N V-mode ring-opening with copper-based organometallics to be assigned.

Nucleophilic vinylic substitution in bicyclic methyleneaziridines: SNVπ or SNVσ?

Nucleophilic vinylic substitution in bicyclic methyleneaziridines: S_NV_π or S_NV_σ?