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A facile approach for the synthesis of bimetallic Au–Pd core–shell nanoparticles with tunable core and shell atoms and their synergistic influences on chemoselective hydrogenation of nitroarenes to anilines and hydration of nitriles to amides.

nanoscale advances

Bimetallic Au–Pd nanoparticles supported on silica with a tunable core@shell structure: enhanced catalytic activity of Pd(core)–Au(shell) over Au(core)–Pd(shell)