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Initial near-equilibrium sodiation in anatase TiO 2  sequentially includes: (1) irreversible phase transition; (2) structural relaxation into amorphous and low-crystallinity products; (3) generation of metallic titanium and sodium plating.

Mechanisms of sodiation in anatase TiO2 in terms of equilibrium thermodynamics and kinetics

Mechanisms of sodiation in anatase TiO₂ in terms of equilibrium thermodynamics and kinetics