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A cost-effective, simple method is developed for m-BiVO 4  hierarchical spheres, which show a higher specific capacitance of 1203 F g −1  at 2 A g −1 , no detectable degradation after 2000 cycles, and beneficial cycling stability due to the unique porous hierarchical architecture.

Fabrication of flower-like bismuth vanadate hierarchical spheres for an improved supercapacitor efficiency