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A halide based three-dimensional hybrid bimetal perovskite shows a reversible structure phase transition accompanied by switchable dielectric properties which provides a new study platform for dielectric materials.

materials advances

An organic–inorganic hybrid double perovskite-type cage-like crystal (MA)<sub>2</sub>KBiCl<sub>6</sub> (MA = methylammonium cation) with dielectric switching behavior

An organic–inorganic hybrid double perovskite-type cage-like crystal (MA)2KBiCl6 (MA = methylammonium cation) with dielectric switching behavior

An organic–inorganic hybrid double perovskite-type cage-like crystal (MA)₂KBiCl₆ (MA = methylammonium cation) with dielectric switching behavior