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Compounds with the Yb 21 Mn 4 Sb 18  structure show local disorder as shown in the PDF model (left) and Cd solid solution provides the highest  zT  (right).

materials advances

The impact of site selectivity and disorder on the thermoelectric properties of Yb21Mn4Sb18 solid solutions: Yb21Mn4−xCdxSb18 and Yb21−yCayMn4Sb18