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From the cubic phase at RT, three superstructures are identified down to 120 K result from the octahedral SnBr 6  tilting and the stereochemical effect of Sn 2+  lone pair. The Seebeck coefficient is ∼2000 μV K −1  at RT.

materials advances

Structural evolution, optical gap and thermoelectric properties of CH3NH3SnBr3 hybrid perovskite, prepared by mechanochemistry