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Mn 2+  occupies [Ca(N,O) 7 ] polyhedral site in Ca-α-SiAlON. The polyhedral site imposes stronger crystal field and nephelauxetic shift on Mn 2+ 4 T 1  →  6 A 1  transition, leading to an intense and broad deep-red emission.

Mn2+ activated Ca-α-SiAlON – broadband deep-red luminescence and sensitization by Eu2+, Yb2+ and Ce3+

Mn²⁺ activated Ca-α-SiAlON – broadband deep-red luminescence and sensitization by Eu²⁺, Yb²⁺ and Ce³⁺