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Catechyl monomers 1-electron-oxidize and undergo radical coupling to produce benzodioxane units in lignin. Derived  o -quinones undergo Diels–Alder reactions giving oxatricyclo and new benzodioxane products, but does this occur in lignification?.

Incorporation of catechyl monomers into lignins: lignification from the non-phenolic endviaDiels–Alder cycloaddition?