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We investigated the performance of Cu nanoclusters in Zr-MOF pores towards direct CO 2  reduction as a function of linker. We found no evidence of electronic promotion but we showed that higher inorganic node acidity favours longer-chain products.

faraday discussions

Effect of linker functionalisation on the catalytic properties of Cu nanoclusters embedded in MOFs in direct CO and CO<sub>2</sub> reduction by H<sub>2</sub>

Effect of linker functionalisation on the catalytic properties of Cu nanoclusters embedded in MOFs in direct CO and CO2 reduction by H2

Effect of linker functionalisation on the catalytic properties of Cu nanoclusters embedded in MOFs in direct CO and CO₂ reduction by H₂