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Reactions of chloromethanes and chlorosilanes EH  x  Cl 4− x   (E = C,  x  = 0–2; E = Si,  x  = 0, 1) with gallanediyl LGa occurred with E–Cl bond insertion and formation of mono- and bis-oxidative addition products.

Geminal C–Cl and Si–Cl bond activation of chloromethanes and chlorosilanes by gallanediyl LGa