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While mesoionic carbenes have usually been shown to improve the catalytic potential of metal complexes, here, we report a switch of selectivity in the nickel-catalyzed coupling of CO 2  and epoxides, now favoring cyclic carbonates over polycarbonates.

Coupling of CO2and epoxides catalysed by novelN-fused mesoionic carbene complexes of nickel(ii)

Coupling of CO₂and epoxides catalysed by novelN-fused mesoionic carbene complexes of nickel(ii)