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Multi-metallic lead calix[4, 6 and 8]arenes have been structurally characterized and employed in the ring opening polymerization of ε-caprolactone (ε-CL), δ-valerolactone (δ-VL) and  r -lactide; the copolymerization of ε-CL and δ-VL was also conducted.

Lead calix[n]arenes (n = 4, 6, 8): structures and ring opening homo-/co-polymerization capability for cyclic esters