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meta -Substituted  N -phenyl, N ′-methyl and  N -benzyl, N ′-methyl imidazolium salts undergo acetate-assisted cyclometallation to provide mixtures of  ortho  and  para  substituted cyclometallated complexes.

dalton transactions

Steric effects on acetate-assisted cyclometallation of meta-substituted N-phenyl and N-benzyl imidazolium salts at [MCl2Cp*]2 (M = Ir, Rh)