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The lanthanide( iii ) complexes (Gd, Eu, Dy, and Yb) of DOTA tris(amide) and bis(amide) derivatives ( L1  and  L2 ) featuring one redox active TEMPO arm were prepared.

Lanthanide complexes of DOTA–nitroxide conjugates for redox imaging: spectroelectrochemistry, CEST, relaxivity, and cytotoxicity